Negatively charged and dark excitons in CsPbBr3 perovskite nanocrystals revealed by high magnetic fields

Abstract : The optical properties of colloidal cesium lead halide perovskite (CsPbBr3) nanocrystals are examined by time-resolved and polarization-resolved spectroscopy in high magnetic fields up to 30 T. We unambiguously show that at cryogenic temperatures the emission is dominated by recombination of negatively charged excitons with radiative decay time of 300 ps. The additional long-lived emission with a decay time of 10-30 ns, which decay time shortens and relative amplitude increases in high magnetic fields, evidence the presence of a dark exciton. We evaluate g-factors of the bright exciton g_X = +2.4, the electron g_e = +2.18 and the hole g_h = -0.22.
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Nano Letters, American Chemical Society, 2017, 17 (10), pp.6177-6183. 〈10.1021/acs.nanolett.7b02827〉
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Damien Canneson, Elena V. Shornikova, Dmitri R. Yakovlev, Tobias Rogge, Anatolie A. Mitioglu, et al.. Negatively charged and dark excitons in CsPbBr3 perovskite nanocrystals revealed by high magnetic fields. Nano Letters, American Chemical Society, 2017, 17 (10), pp.6177-6183. 〈10.1021/acs.nanolett.7b02827〉. 〈hal-01578005〉

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